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Silica Brick

Silica brick is an acidic refractory material with silicon dioxide (SiO₂) as its main component. The SiO₂ content is usually above 93%, and high-quality silica brick can reach above 96%. It uses silica stone (quartzite) as raw material, with mineralizers (such as milk of lime) and binders added, and is fired at 1350~1450℃ after mixing, forming, and drying.

Introduction
Specification
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Introduction

Silica brick is an acidic refractory material with silicon dioxide (SiO₂) as its main component. The SiO₂ content is usually above 93%, and high-quality silica brick can reach above 96%. It uses silica stone (quartzite) as raw material, with mineralizers (such as milk of lime) and binders added, and is fired at 1350~1450℃ after mixing, forming, and drying.

The main mineral composition of silica brick is tridymite, cristobalite, and a small amount of residual quartz and glass phase. During firing, the quartz in the raw material transforms into tridymite and cristobalite. This phase transformation is accompanied by volume expansion, so the firing of silica brick requires strict control of the heating and holding schedule.

Silica brick is a strongly acidic refractory material. It has good resistance to acidic slag and acidic gases, but poor resistance to alkaline slag (especially oxides such as Al₂O₃, K₂O, and Na₂O). Its refractoriness under load is extremely high (1640~1680℃), close to the melting point of tridymite and cristobalite, and it has stable volume and no deformation during long-term high-temperature use.

Specification

According to the national standard GB/T 2608—2025, silica bricks are divided by main application into three major categories: glass furnace, coke oven, and hot blast stove, and are divided into six grades according to physical and chemical indicators.

Grade Naming Rules

In the grade designation, the letters mean: “G” for silica, “B” for glass furnace, “J” for coke oven, and “R” for hot blast stove; the number represents the mass fraction of SiO₂; “a, b” represent product levels, and “H” represents high thermal conductivity.

Main Technical Indicators of Each Grade

Silica Brick for Glass Furnace (BG Series)

Item BG-96a BG-96b BG-95
SiO₂ (%) ≥ 96 96 95
Fe₂O₃ (%) ≤ 0.5 0.8 1.0
Apparent porosity (%) ≤ 21 22 —
True density (g/cm³) ≤ 2.34 2.34 2.34
Cold compressive strength (MPa) ≥ 40 35 30
Refractoriness under load (0.2MPa) start temperature (℃) ≥ 1680 1670 1670

Silica Brick for Coke Oven (JG Series)

Item JG-95H JG-94
SiO₂ (%) ≥ 95 94
Apparent porosity (%) ≤22 ≤24
Cold compressive strength (MPa) ≥ — ≥28~40
Refractoriness under load (0.2MPa) start temperature (℃) ≥ ≥1650 ≥1650
Item RG-95
SiO₂ (%) ≥ 95
Fe₂O₃ (%) ≤ 1.2
Apparent porosity (%) ≤ 22 (24)
True density (g/cm³) ≤ 2.33 (2.34)
Cold compressive strength (MPa) ≥ 40 (30)
Refractoriness under load (0.2MPa) start temperature (℃) ≥ 1650

Silica Brick for Hot Blast Stove (RG Series)

Note: Values in parentheses are indicators for checker bricks.

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Product Advantages

  • Extremely high refractoriness under load
    The refractoriness under load start temperature of silica brick can reach 1640~1680℃, close to its refractoriness (1710~1730℃). It deforms very little under high-temperature load conditions, making it the preferred material for high-temperature load-bearing parts.
  • High-temperature volume stability
    Silica brick has stable volume during long-term high-temperature use. After repeated firing, it does not shrink and may even slightly expand. It can be used continuously for one or even two blast furnace campaigns. The masonry has good airtightness and structural strength.
  • Strong resistance to acidic slag erosion
    It has good resistance to acidic slag, acidic gases, and iron oxides (FeO, Fe₂O₃), making it suitable for acidic smelting environments. In glass furnaces, after the surface is eroded by alkali vapor, a smooth altered layer forms, which actually slows further erosion.
  • Good thermal conductivity
    The thermal conductivity of silica brick is greater than that of clay brick and high-alumina brick, which helps the hot blast stove store and release heat in a shorter time, and is also suitable for coke ovens requiring good thermal conductivity.
  • No contamination of molten glass
    The main component of silica brick is SiO₂. Even if pieces fall off or surface melt droplets fall into the molten glass, the glass quality is not affected. This is an important consideration for selecting silica brick for glass furnaces.
  • Relatively low bulk density
    The bulk density of silica brick is about 1.8~1.95g/cm³, relatively light, which can reduce the furnace body’s own weight and facilitate kiln structure design.

Applications

Silica brick is mainly used in the following key parts of high-temperature industrial kilns:

  • Coke Oven
    The coke oven is the most typical and largest-volume application scenario for silica brick. Silica brick is used to build important parts of the coke oven such as the carbonization chamber, combustion chamber, inclined flue, and regenerator. Its high-temperature volume stability and good thermal conductivity meet the requirements of long-term continuous operation of the coke oven.
  • Glass Melting Furnace
    It is used for the crown (furnace roof), breast wall, flame space, and regenerator arch and checker bricks of glass tank furnaces, as well as other high-temperature parts not in direct contact with molten glass. Silica brick for glass furnaces has higher requirements for purity and resistance to alkali vapor erosion.
  • Blast Furnace Hot Blast Stove
    It is used for high-temperature load-bearing partsof the hot blast stove, including the dome, furnace wall, and checker bricks. Silica brick for hot blast stoves requires low creep rate and can maintain volume stability under long-term high-temperature load conditions.
  • Other Kilns
    It is also used for the arches and load-bearing parts of thermal equipment such as acidic steelmaking furnaces, soaking pits, ceramic firing kilns, and carbon baking furnaces.

Usage Precautions

The biggest disadvantage of silica brick is its low thermal shock resistance. During heating or cooling below 600℃, due to the severe volume change accompanying quartz crystal transformation (significant expansion in the room temperature to 600℃ range), cracks are very likely to occur. Therefore:

The heating and cooling speed must be strictly controlled during furnace drying and shutdown, especially in the stage before 600℃ where expansion is intense, which must be carried out slowly

The silica brick masonry should reserve expansion joints according to the thermal expansion rate provided by the manufacturer

It should be waterproof and moisture-proof during storage. After being wetted, it needs to be slowly dried below 100℃. Water-containing silica brick may affect strength after freezing and needs to be re-inspected

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