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Carbon Brick

Carbon brick is a neutral refractory material made from carbonaceous materials with an appropriate amount of binder. Its main raw materials include anthracite, coke, and graphite, and the binder is usually coal tar pitch, tar, or resin.

Introduction
Specification
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Introduction

Carbon brick is a neutral refractory material made from carbonaceous materials with an appropriate amount of binder. Its main raw materials include anthracite, coke, and graphite, and the binder is usually coal tar pitch, tar, or resin. The carbon mass fraction is generally 88%~90%, and the fixed carbon content of high-quality carbon brick can reach above 95%.

The production process of carbon brick is typically: raw materials are screened, batched, kneaded, formed (molded or extruded), baked (1100~1450℃), precision-milled, and machined. The mineral composition of carbon brick is mainly carbonaceous material. It has the characteristics of not melting and not softening, and only volatilizes at high temperatures (above 3000℃), a temperature that cannot be reached in a blast furnace.

Carbon brick is extremely prone to oxidation under high-temperature conditions, so it is mainly used for lining parts of furnaces that are not exposed to air or oxidizing atmospheres. According to different raw materials and processes, carbon bricks are mainly divided into ordinary carbon brick, semi-graphitic carbon brick, microporous carbon brick, ultra-microporous carbon brick, and self-baking carbon brick, among other varieties.

Specification

Classification by Application

By application scenario, carbon bricks are mainly divided into blast furnace carbon brick, electric furnace carbon brick (submerged arc furnace carbon brick), and aluminum electrolytic cell carbon brick.

Molded carbon brick for blast furnace (designation SM-3MR) is the lining material for key parts of the blast furnace hearth and bottom. It uses electrically calcined anthracite and resin composite binder as main raw materials and has ultra-microporous characteristics. Main physical and chemical indicators are as follows:

Item Unit Indicator Value
Bulk density g/cm³ 1.75
Apparent porosity % 12
Compressive strength MPa 50
Flexural strength MPa 11
Permeability mDa 0.5
Average pore diameter μm 0.05
Pore volume ratio less than 1μm % 83
Thermal conductivity (600℃) W/(mK) 25

Molded carbon brick dimensions for blast furnace:

Dimension/mm Width/mm Height/mm Length/mm
500×400 500 400 <3000
500×500 500 500 <3000
500×600 500 600 <3000
500×700 500 700 <3000

Semi-graphitic carbon brick uses high-temperature electrically calcined anthracite (calcination temperature 1500~2000℃) as the main raw material and medium-temperature pitch as the binder. It is formed and then precision-machined after high-temperature baking. Main performance indicators:

Item Unit Typical Value
Ash content % 6
Bulk density g/cm³ 1.55
Compressive strength MPa 38
Flexural strength MPa 9.8
Apparent porosity % 18
Thermal conductivity W/(m·K) 13.96

Semi-graphitic carbon brick size range: 400×400×(400-1800mm), 400×500×(400-2500mm), 600×650×(600-2000mm), 800×800×(800-1900mm). Various special-shaped carbon blocks can also be processed according to customer requirements.

Low-ash carbon brick (FDG-PD) uses electrically calcined low-ash anthracite as the main raw material. Its main properties are low ash content and a certain thermal conductivity, meeting the needs of blast furnaces, submerged arc furnaces, and electric furnaces:

Item Unit Guaranteed Value Typical Value
Ash content % ≤3.5 3
Bulk density g/cm³ ≥1.57 1.60
Compressive strength MPa ≥35 38
Apparent porosity % ≤15 13
Thermal conductivity (600℃) W/(m·K) ≥10 12

Anti-corrosion carbon brick is divided by process into sintered carbon brick (SJ-1, SJ-2) and pressed carbon brick (YZ-1, YZ-2), suitable for corrosive environments such as chemical acid/alkali storage tanks, reactors, pipeline linings, and electrolytic cells. Main physical and chemical indicators are as follows:

Type Bulk density (kg/m³) Compressive strength (MPa) Ash content (%) Apparent porosity (%)
Sintered SJ-1 ≥1650 ≥65 ≤3 <20
Sintered SJ-2 ≥1500 ≥45 ≤5 <22
Pressed YZ-1 ≥1650 ≥70 ≤2 <10
Pressed YZ-2 ≥1600 ≥50 ≤5 <15
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Product Advantages

  • Extremely high refractoriness, does not melt or soften
    Carbon brick does not melt or soften at high temperatures and only volatilizes above 3000℃. Its refractoriness under load far exceeds that of clay brick (clay brick is about 1400℃). For high-quality carbon brick, there is almost no softening point.
  • Excellent thermal shock resistance, low thermal expansion coefficient
    The thermal expansion coefficient of carbon brick is much lower than that of other refractory materials, and rapid cooling at high temperatures does not produce cracks. This characteristic is especially important for parts easily damaged by cracks (such as the furnace bottom), so furnace bottom bricks are mostly built with carbon brick.
  • Extremely strong slag resistance
    Except for slag with high FeO content, no slag can erode carbon brick. Carbon brick is not wetted by iron or slag, has few chances of nodulation, and has fewer chances of being damaged by reaction with iron slag.
  • High compressive strength, good wear resistance
    The compressive strength of carbon brick can reach 250~500kg/cm², comparable to clay brick. Its wear resistance is not inferior to clay brick, and its high-temperature strength is high.
  • Good thermal and electrical conductivity
    The thermal conductivity of carbon brick is much higher than that of clay brick, especially graphitic carbon brick. This characteristic has a dual effect: high heat loss is a negative effect, but in the lower part of the blast furnace it is conducive to the formation of a slag skull and can reduce cooling water consumption.
  • Additional advantages of microporous carbon brick
    Microporous carbon brick (average pore diameter <0.5μm) not only has the excellent performance of conventional carbon brick but also has good alkali resistance, molten iron corrosion resistance, oxidation resistance, and molten iron penetration resistance. It is mainly used in abnormal erosion zones of blast furnaces and parts with severe annular gap erosion.
  • Good chemical stability
    Carbon brick resists erosion by various acids, alkalis, salts, and organic solvents, and has unique advantages in the anti-corrosion field.

Applications

Carbon brick is widely used in metallurgy, chemicals, environmental protection, and other industrial fields:

Metallurgy Industry

  • Blast furnace: Linings for core parts such as hearth, crucible, belly, and lower stack; this is the largest application scenario for blast furnace carbon brick
  • Electric furnace / submerged arc furnace: Lining masonry and conductive material for submerged arc furnaces such as calcium carbide furnaces, ferroalloy furnaces, ferrosilicon furnaces, and silicomanganese furnaces
  • Aluminum electrolytic cell: Bottom carbon blocks and side carbon blocks, utilizing their excellent electrical conductivity and molten salt corrosion resistance

Chemical Industry

  • Acid/alkali storage tank lining: Resists corrosion by sulfuric acid, hydrochloric acid, sodium hydroxide, etc.
  • Reactor/pipeline lining: Prevents medium penetration and extends equipment life

Environmental Engineering

Flue gas desulfurization (FGD) systems: Resists acidic slurry corrosion

Waste incineration furnaces: Resists corrosion by acidic gases such as HCl and SO₂

Electroplating and Electronics Industry

Electroplating tanks: Resists strong acid plating solutions (such as chromic acid and hydrofluoric acid)

Semiconductor equipment: High-purity carbon brick is used in corrosive gas environments

Others

Industrial pickling tanks, electroplating tanks, dissolving tanks in the paper industry, petrochemical autoclaves, etc.

Usage Precautions

Carbon brick is extremely prone to oxidation in oxidizing atmospheres, so it is mainly used for lining parts of furnaces that are not exposed to air or oxidizing atmospheres. In ferroalloy production, carbon brick is mainly used for the furnace wall and bottom of submerged arc furnaces that are not exposed to air. When carbon brick is used in blast furnaces, cooling water jackets are usually still required, because the hearth is easily damaged when carbon brick quality is poor, and without cooling water jackets, iron and slag breakout accidents may occur.

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