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Corundum Brick

Corundum brick is an advanced refractory material with aluminum oxide (Al₂O₃) as its main component and corundum as its main mineral phase. Its Al₂O₃ content is usually above 90%. It is also called alumina refractory product. Corundum (α-Al₂O₃) is the most stable structure among the various forms of aluminum oxide, with a melting point as high as 2050℃, a density of about 3.96~4.01 g/cm³, belonging to the hexagonal crystal system, and possessing extremely high cold and high-temperature strength as well as excellent chemical stability.

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Introduction

Corundum brick is an advanced refractory material with aluminum oxide (Al₂O₃) as its main component and corundum as its main mineral phase. Its Al₂O₃ content is usually above 90%. It is also called alumina refractory product. Corundum (α-Al₂O₃) is the most stable structure among the various forms of aluminum oxide, with a melting point as high as 2050℃, a density of about 3.96~4.01 g/cm³, belonging to the hexagonal crystal system, and possessing extremely high cold and high-temperature strength as well as excellent chemical stability.

By preparation process, corundum bricks are mainly divided into two major categories: sintered corundum brick and fused corundum brick. Sintered corundum brick uses sintered alumina clinker as raw material and is fired at 1750~1800℃ after high-pressure forming; fused corundum brick uses fused corundum as raw material, or directly pours molten corundum into molds to form fused-cast bricks. In addition, depending on the additives, derivatives such as chrome corundum brick, zirconia corundum brick, and titania corundum brick can also be produced.

Specification

Grade Classification

Corundum bricks are classified by Al₂O₃ content and additive components. Common varieties and physical and chemical indicators are as follows:

Item High-Purity Corundum Brick DL-98 Ordinary Corundum Brick DL-95 Ordinary Corundum Brick DL-90 Mullite Corundum Brick MDL-80 Chrome Corundum Brick GDL-85
Al₂O₃ (%) ≥ 98.5 95 90 80 85
Cr₂O₃ (%) ≥ — — — — 8
SiO₂ (%) ≤ 0.3 3.0 9.0 18 0.2
Fe₂O₃ (%) ≤ 0.2 0.2 0.5 0.5 0.2
Bulk density (g/cm³) ≥ 3.0 2.9 2.9 2.7 3.1
Cold compressive strength (MPa) ≥ 75 100 100 60 80
Refractoriness (℃) ≥ 1790 1790 1790 1790 1790
Refractoriness under load (℃, 0.2MPa) ≥ 1700 1650 1650 1700 1700
Thermal stability (1100℃ water cooling, cycles) ≥ 6 10 10 20 15

The industry standard YB/T 4348-2013 (2017) specifies corundum brick grades including GYZ-99A, GYZ-99B, GYZ-98, GYZ-95, etc. Among them, GYZ-99A has Al₂O₃≥99.0%, Fe₂O₃≤0.10%, bulk density≥3.20 g/cm³, and compressive strength≥80 MPa.

Dimensional Specifications

The standard brick shape for corundum brick is 230×114×65mm (T-3 type). Various special-shaped products can be customized according to customer drawings. Common market specifications also include 230×115×65mm, 380×150×75mm, 345×114×65mm, etc.

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Product Advantages

  • Extremely high refractoriness
    The refractoriness of corundum brick can reach above 1790℃, and high-purity products can be used at temperatures up to 1800℃. Corundum has a melting point as high as 2050℃ and can maintain structural stability in ultra-high temperature environments.
  • High cold and high-temperature strength
    Corundum brick has very high cold compressive strength (up to 340MPa) and high-temperature strength, with good mechanical strength and wear resistance, and can withstand mechanical loads and wear at high temperatures.
  • Excellent chemical stability
    It has strong resistance to acidic slag, basic slag, metal melts, and molten glass, and is not affected by reducing gases such as H₂ and CO.
  • Good high-temperature creep resistance
    The creep rate of high-purity corundum brick under 1550℃×50h conditions can be as low as 0.5%. It has good high-temperature volume stability and is not easily deformed during long-term use.
  • High purity, no contamination of products
    High-purity low-silica corundum brick has SiO₂<0.5% and Al₂O₃>98%. It does not contaminate products in applications sensitive to impurities, such as petrochemicals and electronic ceramics.
  • Rich variety, strong adaptability
    By adding components such as Cr₂O₃, ZrO₂, TiO₂, and MgO, erosion resistance and thermal shock stability can be improved to meet different working condition requirements.

Applications

Due to its excellent high-temperature performance, corundum brick is widely used in various high-temperature industrial kilns and thermal equipment:

Metallurgy Industry

  • Blast furnace and hot blast stove: Linings for key parts such as stack, hearth, and crucible
  • Secondary refining furnace: Linings for secondary refining equipment
  • Slide gate: Corundum slide plate bricks
  • Induction furnace: High-temperature induction furnace lining

Petrochemical Industry

  • Gas producer and gasifier: Key refractory lining material for gas producers and reaction furnaces in the petrochemical industry, capable of replacing imported products
  • Ammonia synthesis secondary reformer: Lining for secondary reformers in large fertilizer plants
  • Carbon black reaction furnace: Lining for high-temperature reaction furnaces in the carbon black industry

Glass Industry

  • Glass melting furnace: Fused-cast corundum bricks are used for the cooling section tank wall, furnace bottom, and float glass flow channel of glass melting furnaces

Other Fields

  • Ultra-high temperature electric furnace and kiln: Linings for ultra-high temperature electric furnaces above 1600℃
  • Ceramic sintering furnace: High-temperature sintering of zirconia ceramics, electronic ceramics, and magnetic materials
  • Chemical and electronic industry: High-temperature furnace tubes, furnace cores, etc.
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